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1,1-Dichloroethylene

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Manfred Rossberg, Wilhelm Lendle, Gerhard Pfleiderer, Adolf Tögel, Eberhard-Ludwig Dreher, Ernst Langer, Heinz Rassaerts, Peter Kleinschmidt, Heinz Strack, Richard Cook, Uwe Beck, Karl-August Lipper, Theodore R. Torkelson, Eckhard Löser, Klaus K. Beutel, Trevor Mann "Chlorinated Hydrocarbons" in
874:. During the 1990s research suggested that, in common with many chlorinated carbon compounds, Saran posed a possible danger to health by leaching, especially on exposure to food in microwave ovens. Accordingly, Saran changed their formulation in 2004 to a form of 541: 548: 748:. It is a colorless liquid with a sharp odor. Like most chlorocarbons, it is poorly soluble in water but soluble in organic solvents. 1,1-DCE was the precursor to the original 897: 1021: 526: 534: 955: 901: 630: 703: 1069: 333: 893: 698: 17: 308: 829: 710: 972: 890:, including symptoms of sedation, inebriation, convulsions, spasms, and unconsciousness at high concentrations. 1098: 1093: 251: 194: 48: 272: 654: 641: 289: 136: 863: 853: 442: 38: 1088: 887: 769: 765: 260: 68: 176: 8: 808:
The gas phase reaction, without the base, would be more desirable but is less selective.
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Course CEIC2004 Industrial Chemistry for Engineers. Chemistry Lecture Notes, UNSW
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The health effects from exposure to vinylidene chloride are primarily on the
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Ullmann's Encyclopedia of Industrial Chemistry 2006, Wiley-VCH, Weinheim.
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Except where otherwise noted, data are given for materials in their
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1,1-DCE is mainly used as a comonomer in the polymerization of
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considers vinylidene chloride a potential occupational
768:, a relatively unwanted byproduct in the production of 756:, for food, but this application has been phased out. 956:
National Institute for Occupational Safety and Health
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National Institute for Occupational Safety and Health
1080: 1070:Agency for Toxic Substances and Disease Registry 1022:"CEO explains why SC Johnson hobbled Saran Wrap" 239: 522: 111: 973:"Toxicological Review of 1,1-Dichloroethylene" 764:1,1-DCE is produced by dehydrochlorination of 980:United States Environmental Protection Agency 866:. A very widely used product, cling wrap, or 1056:CDC - NIOSH Pocket Guide to Chemical Hazards 967: 965: 900:, meaning possibly carcinogenic to humans. 894:International Agency for Research on Cancer 565:−22.8 °C (−9.0 °F; 250.3 K) 847: 292: 197: 175: 962: 259: 950:NIOSH Pocket Guide to Chemical Hazards. 404:−122 °C (−188 °F; 151 K) 288: 14: 1081: 945: 943: 941: 939: 937: 188: 1019: 862:, 1,1-DCE can be polymerised to form 320:Key: LGXVIGDEPROXKC-UHFFFAOYSA-N 155: 414:32 °C (90 °F; 305 K) 934: 780:with temperature ca. 100 °C. 230: 214: 24: 518: 47: 37: 25: 1110: 1063: 830:semiconductor device fabrication 688: 896:has put vinylidene chloride in 811: 684:(at 25 °C , 100 kPa). 1049: 1038: 1013: 995: 986: 317:InChI=1S/C2H2Cl2/c1-2(3)4/h1H2 13: 1: 1020:Burke, Michael (2015-04-25). 1008:10.1002/14356007.a06_233.pub2 982:. Washington, D.C. June 2002. 928: 759: 635:(US health exposure limits): 7: 911: 737:with the molecular formula 583:or concentration (LD, LC): 90:Asymmetrical dichloroethene 33: 10: 1115: 851: 881: 678: 629: 579: 500: 468: 384:96.94 g/mol 349: 329: 304: 95: 79: 67: 62: 32: 832:for growing high purity 625:1,000 ppm (rat, 2.4 hr) 623:98 ppm (mouse, 22–23 hr) 864:polyvinylidene chloride 854:polyvinylidene chloride 848:Polyvinylidene chloride 443:Magnetic susceptibility 888:central nervous system 828:. It is also used in 529: 53: 43: 770:1,1,1-trichloroethane 766:1,1,2-trichloroethane 621:200 ppm (rat, 4.1 hr) 528: 88:Vinylidene dichloride 51: 41: 28:1,1-Dichloroethylene 1099:Vinylidene compounds 1094:Halogenated solvents 792:Cl + NaOH → Cl 723:1,1-Dichloroethylene 511:(fire diamond) 82:1,1-Dichloroethylene 69:Preferred IUPAC name 52:Ball-and-stick model 870:was made from this 858:As with many other 727:vinylidene chloride 421:Solubility in water 86:Vinylidene chloride 29: 18:Vinylidene chloride 1074:1,1-Dichloroethene 918:1,2-Dichloroethene 774:1,2-dichloroethane 725:, commonly called 711:Infobox references 670:(Immediate danger) 603:194 mg/kg (mouse) 530: 73:1,1-Dichloroethene 54: 44: 42:Structural formula 27: 719:Chemical compound 717: 716: 426:2,240mg/L (25°C) 273:CompTox Dashboard 137:Interactive image 58: 57: 16:(Redirected from 1106: 1058: 1053: 1047: 1042: 1036: 1035: 1033: 1032: 1017: 1011: 999: 993: 990: 984: 983: 977: 969: 960: 959: 947: 747: 701: 695: 692: 691: 615:lowest published 601:1500 mg/kg (rat) 595:lowest published 571:Explosive limits 550: 543: 536: 521: 449:-49.2·10 cm/mol 436:500 mmHg (20°C) 357:Chemical formula 297: 296: 281: 279: 263: 243: 232: 218: 201: 190: 179: 159: 139: 115: 34: 30: 26: 21: 1114: 1113: 1109: 1108: 1107: 1105: 1104: 1103: 1079: 1078: 1066: 1061: 1054: 1050: 1043: 1039: 1030: 1028: 1018: 1014: 1000: 996: 991: 987: 975: 971: 970: 963: 948: 935: 931: 914: 884: 856: 850: 839: 834:silicon dioxide 814: 803: 799: 795: 791: 787: 779: 762: 746: 742: 738: 720: 713: 708: 707: 706:  ?) 697: 693: 689: 685: 671: 658: 645: 624: 622: 618: 612: 602: 598: 592: 555: 554: 553: 552: 545: 538: 531: 527: 519: 493: 491:Molecular shape 484: 478: 458: 446: 423: 373: 369: 365: 359: 345: 342: 337: 336: 325: 322: 321: 318: 312: 311: 300: 282: 275: 266: 246: 233: 221: 182: 162: 142: 129: 118: 105: 91: 89: 87: 85: 83: 75: 74: 23: 22: 15: 12: 11: 5: 1112: 1102: 1101: 1096: 1091: 1077: 1076: 1065: 1064:External links 1062: 1060: 1059: 1048: 1037: 1012: 994: 985: 961: 932: 930: 927: 926: 925: 923:Dichloroethane 920: 913: 910: 883: 880: 852:Main article: 849: 846: 837: 818:vinyl chloride 813: 810: 806: 805: 801: 797: 793: 789: 785: 777: 761: 758: 744: 740: 735:organochloride 718: 715: 714: 709: 687: 686: 682:standard state 679: 676: 675: 672: 666: 663: 662: 659: 653: 650: 649: 646: 640: 637: 636: 627: 626: 619: 610: 608: 605: 604: 599: 590: 588: 585: 584: 577: 576: 573: 567: 566: 563: 557: 556: 546: 539: 532: 517: 516: 515: 514: 512: 503: 502: 498: 497: 494: 489: 486: 485: 482: 479: 474: 471: 470: 466: 465: 459: 454: 451: 450: 447: 441: 438: 437: 434: 432:Vapor pressure 428: 427: 424: 419: 416: 415: 412: 406: 405: 402: 396: 395: 392: 386: 385: 382: 376: 375: 371: 367: 363: 360: 355: 352: 351: 347: 346: 344: 343: 340: 332: 331: 330: 327: 326: 324: 323: 319: 316: 315: 307: 306: 305: 302: 301: 299: 298: 285: 283: 271: 268: 267: 265: 264: 256: 254: 248: 247: 245: 244: 236: 234: 226: 223: 222: 220: 219: 211: 209: 203: 202: 192: 184: 183: 181: 180: 172: 170: 164: 163: 161: 160: 152: 150: 144: 143: 141: 140: 132: 130: 123: 120: 119: 117: 116: 108: 106: 101: 98: 97: 93: 92: 81: 77: 76: 72: 71: 65: 64: 60: 59: 56: 55: 45: 9: 6: 4: 3: 2: 1111: 1100: 1097: 1095: 1092: 1090: 1089:Chloroalkenes 1087: 1086: 1084: 1075: 1071: 1068: 1067: 1057: 1052: 1046: 1041: 1027: 1026:Journal Times 1023: 1016: 1009: 1005: 998: 989: 981: 974: 968: 966: 957: 953: 946: 944: 942: 940: 938: 933: 924: 921: 919: 916: 915: 909: 907: 903: 899: 895: 891: 889: 879: 877: 873: 869: 865: 861: 855: 845: 843: 835: 831: 827: 823: 822:acrylonitrile 819: 809: 800:+ NaCl + H 783: 782: 781: 775: 771: 767: 757: 755: 751: 736: 732: 728: 724: 712: 705: 700: 683: 677: 673: 669: 665: 664: 660: 657:(Recommended) 656: 652: 651: 647: 644:(Permissible) 643: 639: 638: 634: 633: 628: 620: 616: 607: 606: 600: 596: 587: 586: 582: 578: 574: 572: 569: 568: 564: 562: 559: 558: 551: 544: 537: 513: 510: 509: 505: 504: 499: 495: 492: 488: 487: 480: 477: 473: 472: 467: 464: 460: 457: 456:Dipole moment 453: 452: 448: 444: 440: 439: 435: 433: 430: 429: 425: 422: 418: 417: 413: 411: 410:Boiling point 408: 407: 403: 401: 400:Melting point 398: 397: 393: 391: 388: 387: 383: 381: 378: 377: 361: 358: 354: 353: 348: 339: 338: 335: 328: 314: 313: 310: 303: 295: 291: 290:DTXSID8021438 287: 286: 284: 274: 270: 269: 262: 258: 257: 255: 253: 250: 249: 242: 238: 237: 235: 229: 225: 224: 217: 213: 212: 210: 208: 205: 204: 200: 196: 193: 191: 189:ECHA InfoCard 186: 185: 178: 174: 173: 171: 169: 166: 165: 158: 154: 153: 151: 149: 146: 145: 138: 134: 133: 131: 127: 122: 121: 114: 110: 109: 107: 104: 100: 99: 94: 78: 70: 66: 61: 50: 46: 40: 36: 35: 31: 19: 1051: 1040: 1029:. Retrieved 1025: 1015: 997: 988: 979: 892: 885: 876:polyethylene 857: 815: 812:Applications 807: 763: 730: 726: 722: 721: 631: 580: 507: 96:Identifiers 80:Other names 581:Lethal dose 561:Flash point 476:Point group 394:1.213 g/cm 350:Properties 195:100.000.786 157:CHEBI:34031 1083:Categories 1031:2024-09-18 929:References 906:carcinogen 760:Production 575:6.5–15.5% 469:Structure 380:Molar mass 261:21SK105J9D 168:ChemSpider 124:3D model ( 103:CAS Number 826:acrylates 750:clingwrap 341:ClC(Cl)=C 958:(NIOSH). 912:See also 898:Class 2B 733:, is an 508:NFPA 704 501:Hazards 445:(χ) 1045:epa.gov 952:"#0661" 872:polymer 860:alkenes 731:1,1-DCE 704:what is 702: ( 496:Planar 390:Density 374: 228:PubChem 113:75-35-4 84:1,1-DCE 882:Safety 824:, and 699:verify 696:  334:SMILES 216:C14039 63:Names 976:(PDF) 868:Saran 842:films 754:Saran 648:none 632:NIOSH 309:InChI 148:ChEBI 126:JSmol 836:(SiO 796:C=CH 788:CHCH 772:and 739:CHCl 674:Ca 668:IDLH 461:1.3 252:UNII 241:6366 207:KEGG 177:6126 1004:doi 729:or 661:Ca 655:REL 642:PEL 278:EPA 231:CID 1085:: 1072:: 1024:. 978:. 964:^ 954:. 936:^ 908:. 878:. 844:. 840:) 820:, 784:Cl 752:, 743:CH 611:Lo 609:LC 591:Lo 589:LD 483:2v 370:Cl 1034:. 1010:. 1006:: 838:2 804:O 802:2 798:2 794:2 790:2 786:2 778:2 745:3 741:2 694:N 617:) 613:( 597:) 593:( 549:2 542:4 535:2 481:C 463:D 372:2 368:2 366:H 364:2 362:C 280:) 276:( 128:) 20:)

Index

Vinylidene chloride
Structural formula
Ball-and-stick model
Preferred IUPAC name
CAS Number
75-35-4
JSmol
Interactive image
ChEBI
CHEBI:34031
ChemSpider
6126
ECHA InfoCard
100.000.786
Edit this at Wikidata
KEGG
C14039
PubChem
6366
UNII
21SK105J9D
CompTox Dashboard
DTXSID8021438
Edit this at Wikidata
InChI
SMILES
Chemical formula
Molar mass
Density
Melting point

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