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Stilbite

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980: 968: 29: 992: 1004: 1016: 1388: 568:. The twofold axis is the crystal axis b, and the a and c crystal axes lie in the mirror plane. For a monoclinic crystal a and c are inclined to each other at an angle β which is not a right angle. For stilbite β is nearly 130°. Stilbite crystals, however, appear to be almost 979: 489:
ions occupy equivalent sites and can substitute for each other. Since silicon and aluminium have a different charge (Si and Al) the ions occupying the sodium/calcium site have to adjust to maintain charge balance. There is a continuous
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can be chosen, containing two formula units (Z = 2) such that resembles an orthorhombic cell, with all three crystal axes very nearly mutually perpendicular. The mineral is said to be pseudo-orthorhombic.
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and stilbite were considered to be identical minerals. After they were found to be two separate species, in 1818, the name desmine ("a bundle") was proposed for stilbite, and this name is still employed in
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for stilbite-Ca. It is presumed to be the Helgusta Iceland Spar Mine, along Reydarfjordur. Excellent white bow ties of stilbite are found here on calcite and quartz, associated with heulandite and
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Cruciani, Giuseppe; Artioli, Gilberto; Gualtieri, Alessandro; Stahl, Kenny; Hanson, Jonathan C. (1 August 1997). "Dehydration dynamics of stilbite using synchrotron X-ray powder diffraction".
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O). In the case of stilbite-Na, sodium dominates over calcium. The species are visually indistinguishable, and the series name stilbite is still used whenever testing has not been performed.
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can be considered as a monoclinic cell with β close to 130° and one formula unit per unit cell (Z = 1), or as a larger pseudo-orthorhombic cell with β close to 90° and Z = 2.
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a = 13.595 to 13.657 Å, b = 18.197 to 18.309 Å, c = 17.775 to 17.842 Å, β = 90:05 to 90.91° (Z is doubled to Z = 4 because the formula unit halved to NaCa
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Clustered on a matrix of white chalcedony are a group of light salmon stilbite crystals; adjoining is a cluster of mint green fluorapophyllite crystals
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Deccan basalts of western India are the most prolific sources of stilbite in the world. Stilbite is the most abundant zeolite in the
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or even truly orthorhombic, indeed the framework can have symmetry ranging from orthorhombic to triclinic in a single crystal.
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Nx = 1.479 to 1.492, Ny = 1.485 to 1.500, Nz = 1.489 to 1.505 Nx = 1.484 to 1.500, Ny = 1.492 to 1.507, Nz = 1.494 to 1.513
1479: 1469: 1285: 469:. The English name "stilbite" is from the Greek stilbein = to shine, because of the pearly luster of the {010} faces. 1224: 744:. It has 10-member rings and 8-member rings forming channels parallel to a and pseudo-orthorhombic c respectively. 1424: 615:
The color is usually colorless or white, also yellow, brown, pink, salmon, orange, red, green, blue or black. The
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Intergrown pinkish stilbite crystals showing the "bow-tie" tendency from Jalgaon District, Maharashtra, India.
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and elongated along the a axis. Aggregates may be sheaf-like or in bow-ties, also fibrous and globular.
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Stilbite-Ca, by far the more common of the two, is a hydrous calcium sodium and aluminium silicate,
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Where sources give cell parameters for stilbite-Na, they are the same as those for stilbite-Ca.
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a = 13.595 to 13.69 Å, b = 18.197 to 18.31 Å, c = 11.265 to 11.30 Å, β = 127.94 to 128.1°
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is perfect on {010}, poor on {001}. The mineral is brittle, with a conchoidal or uneven
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a = 13.595 to 13.69 Å, b = 18.197 to 18.31 Å, c = 17.775 to 17.86 Å, β = 90.00 to 90.91°
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a = 13.60 to 13.69 Å, b = 18.20 to 18.31 Å, c = 17.78 to 17.86 Å, β = 90.0 to 90.91°
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The framework of stilbite is pseudo-orthorhombic with the open channels typical of
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Thin tabular, aggregates sheaf-like or in bow-ties, also fibrous and globular.
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Stilbite crystal aggregates in fan shapes from Wassons Bluff, Nova Scotia.
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deposits or deep-sea deposits. Associated minerals are other zeolites,
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Reddish-orange Stilbite-Ca from Jalgaon District, Maharashtra, India
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Green Stilbite-Ca, which gets its color from inclusions of celadonite
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O), and stilbite, and another continuous series between stilbite and
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changed it to a series name, with the mineral species being named:
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This article incorporates text from a publication now in the
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Rudy W. Tschernich (1992) Zeolites of the World. Geoscience Press
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a = 13.60 to 13.69 Å, b = 18.20 to 18.31 Å, c = 11.27 Å, β = 128°
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in large fractures and cavities in the highly weathered volcanic
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and Pune and decreases in abundance toward the coast at Mumbai.
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Gaines et al (1997) Dana’s New Mineralogy Eighth Edition. Wiley
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are typically thin tabular, flattened parallel to the dominant
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Easily fused by blowpipe (~1050 °C) to produce a white "enamel"
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Nx = 1.484 to 1.500, Ny = 1.492 to 1.507, Nz = 1.494 to 1.513
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Nx = 1.479 to 1.492, Ny = 1.485 to 1.500, Nz = 1.489 to 1.505
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parallel to the plane of symmetry it is markedly pearly. The
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is white and crystals are transparent to translucent. The
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The open channels in the stilbite structure act like a
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is a distinct zeolite species unrelated to stilbite.
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a = 13.63 Å, b = 18.17 Å, c = 11.31 Å, β = 129.166°
1363: 396:group. Prior to 1997, stilbite was recognized as a 703:Cell parameters for the pseudo-orthorhombic cell: 610: 1431: 1215:Klein, Cornelis and Cornelius S. Hurlbut, 1985, 913:The type locality for stilbite-Na is Cape Pula, 477:Stilbite shows a wide variation in exchangeable 472: 883:; white sheaf-like groups encrust the calcite ( 855:(where it is the provincial mineral), northern 400:species, but a reclassification in 1997 by the 835:Stilbite is abundant in the volcanic rocks of 811:. Stilbite has not been found in sedimentary 863:. Salmon-pink crystals occur with pale green 560:2/m, meaning that it has one twofold axis of 1413:(11th ed.). Cambridge University Press. 1265: 1263: 1250: 1248: 1140: 1138: 1136: 1134: 1119: 1117: 1115: 1113: 902:Iceland is generally considered to be the 733:a=13.69 Å, b=18.25 Å, c=11.31 Å, β =128.2° 689:Cell Parameters for the monoclinic cell: 675: 619:is generally vitreous, and on the perfect 16:Tectosilicate mineral of the zeolite group 1283: 1065: 1360:American Mineralogist (1970) 55: 387–397 776:hydrothermal mineral. It occurs in the 1398: 1369: 1356: 1354: 1260: 1245: 1211: 1209: 1131: 1110: 402:International Mineralogical Association 1432: 1238: 1236: 1234: 1232: 1198:: CS1 maint: archived copy as title ( 1163: 1161: 1159: 1157: 1155: 1153: 1351: 1206: 1103: 1101: 1099: 1097: 1095: 1093: 1091: 1089: 1087: 1085: 1042:"IMA–CNMNC approved mineral symbols" 1039: 498:, whose formula can be written as Ca 1255:http://www.mindat.org/min-7314.html 1229: 1145:http://www.mindat.org/min-7313.html 803:, and as a cementing agent in some 13: 1150: 14: 1491: 1418: 1082: 1399:Spencer, Leonard James (1911). " 1386: 1014: 1002: 990: 978: 966: 959: 551: 216:Usually colorless, white or pink 27: 1308: 1286:"Crystal structure of stilbite" 1277: 611:Physical and optical properties 155:also triclinic and orthorhombic 1033: 772:Stilbite is a low-temperature 767: 1: 1026: 830: 660:Stilbite is biaxial (-) with 473:Chemistry and related species 7: 388:is the name of a series of 10: 1496: 1480:Minerals in space group 63 1470:Minerals in space group 12 1271:"Stilbite-Na Mineral Data" 1125:"Stilbite-Ca Mineral Data" 756:, enabling it to separate 657:. It is not radioactive. 455: 322:Transparent to translucent 584:forms of stilbite may be 374: 364: 354: 344: 336: 326: 316: 306: 302:Vitreous, pearly on {010} 296: 270: 260: 250: 240: 230: 220: 212: 206:Stilbite-Ca: 2,840 g/mol 200: 195: 177: 159: 144: 134: 120: 110: 54: 40: 35: 26: 21: 591: 208:Stilbite-Na: 2,864 g/mol 1410:Encyclopædia Britannica 747: 676:Unit cell and structure 1284:Slaughter, M. (1970). 1046:Mineralogical Magazine 1475:Orthorhombic minerals 1337:10.2138/am-1997-7-810 1317:American Mineralogist 1290:American Mineralogist 1217:Manual of Mineralogy, 122:Strunz classification 889:Paterson, New Jersey 801:hot springs deposits 556:Stilbite is usually 256:Conchoidal or uneven 236:Very common on {001} 1465:Monoclinic minerals 1329:1997AmMin..82..729C 1219:Wiley, pp. 465–466 1067:10.1180/mgm.2021.43 1058:2021MinM...85..291W 1040:Warr, L.N. (2021). 799:. It also forms in 564:perpendicular to a 562:rotational symmetry 136:Dana classification 1455:Aluminium minerals 1425:Structure type STI 797:hydrothermal veins 762:petroleum refining 760:in the process of 662:refractive indices 337:Optical properties 950:tholeiitic basalt 383: 382: 370:Decomposes in HCl 246:Perfect on {010} 173: 130: 64:Stilbite-Ca: NaCa 1487: 1450:Calcium minerals 1414: 1392: 1390: 1389: 1373: 1367: 1361: 1358: 1349: 1348: 1323:(7–8): 729–739. 1312: 1306: 1305: 1303: 1301: 1281: 1275: 1274: 1267: 1258: 1252: 1243: 1240: 1227: 1213: 1204: 1203: 1197: 1189: 1187: 1186: 1180: 1174:. Archived from 1173: 1165: 1148: 1142: 1129: 1128: 1121: 1108: 1105: 1080: 1079: 1069: 1037: 1018: 1006: 994: 982: 970: 647:specific gravity 644: 643: 639: 636: 392:minerals of the 346:Refractive index 328:Specific gravity 291: 290: 286: 283: 276: 167: 165:Prismatic (2/m) 129:8/J.23-30 (8 ed) 128: 126:9.GE.10 (10 ed) 61: 60:(repeating unit) 31: 19: 18: 1495: 1494: 1490: 1489: 1488: 1486: 1485: 1484: 1445:Sodium minerals 1430: 1429: 1421: 1387: 1385: 1377: 1376: 1368: 1364: 1359: 1352: 1313: 1309: 1299: 1297: 1282: 1278: 1269: 1268: 1261: 1253: 1246: 1241: 1230: 1214: 1207: 1191: 1190: 1184: 1182: 1178: 1171: 1169:"Archived copy" 1167: 1166: 1151: 1143: 1132: 1123: 1122: 1111: 1106: 1083: 1038: 1034: 1029: 1022: 1019: 1010: 1007: 998: 995: 986: 983: 974: 971: 962: 833: 770: 754:molecular sieve 750: 729: 725: 721: 717: 713: 688: 678: 649:2.12 to 2.22. 641: 637: 634: 632: 613: 594: 572:, and a larger 554: 541: 537: 533: 529: 525: 517: 513: 509: 505: 501: 475: 458: 451: 444: 437: 431: 424: 288: 284: 281: 279: 274: 207: 187: 166: 154: 127: 105: 101: 97: 93: 89: 86:Stilbite-Na: Na 85: 83: 79: 75: 71: 67: 59: 58: 17: 12: 11: 5: 1493: 1483: 1482: 1477: 1472: 1467: 1462: 1457: 1452: 1447: 1442: 1440:Tectosilicates 1428: 1427: 1420: 1419:External links 1417: 1416: 1415: 1405:Chisholm, Hugh 1382: 1381: 1375: 1374: 1362: 1350: 1307: 1276: 1259: 1244: 1228: 1205: 1149: 1130: 1109: 1081: 1052:(3): 291–320. 1031: 1030: 1028: 1025: 1024: 1023: 1020: 1013: 1011: 1008: 1001: 999: 996: 989: 987: 984: 977: 975: 972: 965: 961: 958: 952:plateaux near 861:North Carolina 832: 829: 785:volcanic rocks 769: 766: 749: 746: 738: 737: 734: 731: 727: 723: 719: 715: 711: 708: 701: 700: 697: 694: 677: 674: 673: 672: 669: 612: 609: 593: 590: 553: 550: 539: 535: 531: 527: 523: 515: 511: 507: 503: 499: 474: 471: 457: 454: 449: 442: 435: 429: 422: 413: 412: 409: 381: 380: 376: 372: 371: 368: 362: 361: 358: 352: 351: 348: 342: 341: 338: 334: 333: 330: 324: 323: 320: 314: 313: 310: 304: 303: 300: 294: 293: 277: 268: 267: 264: 258: 257: 254: 248: 247: 244: 238: 237: 234: 228: 227: 224: 218: 217: 214: 210: 209: 204: 198: 197: 196:Identification 193: 192: 191:(orthorhombic) 181: 175: 174: 163: 157: 156: 148: 146:Crystal system 142: 141: 138: 132: 131: 124: 118: 117: 114: 108: 107: 103: 99: 95: 91: 87: 81: 77: 73: 69: 65: 62: 52: 51: 42: 38: 37: 33: 32: 24: 23: 15: 9: 6: 4: 3: 2: 1492: 1481: 1478: 1476: 1473: 1471: 1468: 1466: 1463: 1461: 1458: 1456: 1453: 1451: 1448: 1446: 1443: 1441: 1438: 1437: 1435: 1426: 1423: 1422: 1412: 1411: 1406: 1402: 1396: 1395:public domain 1384: 1383: 1379: 1378: 1371: 1366: 1357: 1355: 1346: 1342: 1338: 1334: 1330: 1326: 1322: 1318: 1311: 1295: 1291: 1287: 1280: 1272: 1266: 1264: 1256: 1251: 1249: 1239: 1237: 1235: 1233: 1226: 1225:0-471-80580-7 1222: 1218: 1212: 1210: 1201: 1195: 1181:on 2020-03-29 1177: 1170: 1164: 1162: 1160: 1158: 1156: 1154: 1146: 1141: 1139: 1137: 1135: 1126: 1120: 1118: 1116: 1114: 1104: 1102: 1100: 1098: 1096: 1094: 1092: 1090: 1088: 1086: 1077: 1073: 1068: 1063: 1059: 1055: 1051: 1047: 1043: 1036: 1032: 1017: 1012: 1005: 1000: 993: 988: 981: 976: 969: 964: 963: 960:Photo gallery 957: 955: 951: 947: 942: 940: 936: 932: 928: 924: 920: 916: 911: 910:in cavities. 909: 905: 904:type locality 900: 898: 894: 893:United States 890: 886: 882: 878: 875:(Bombay) and 874: 870: 866: 862: 858: 854: 850: 846: 842: 841:Faroe Islands 838: 828: 826: 822: 818: 814: 810: 809:conglomerates 806: 802: 798: 794: 790: 786: 783: 779: 775: 765: 763: 759: 755: 745: 743: 735: 732: 709: 706: 705: 704: 698: 695: 692: 691: 690: 686: 681: 670: 667: 666: 665: 663: 658: 656: 652: 648: 645:to 4 and the 630: 626: 622: 618: 608: 606: 602: 598: 589: 587: 583: 578: 575: 571: 567: 563: 559: 552:Crystal class 549: 547: 543: 521: 497: 493: 488: 484: 480: 470: 468: 463: 453: 448: 441: 434: 428: 421: 418: 410: 407: 406: 405: 403: 399: 395: 391: 390:tectosilicate 387: 379: 377: 373: 369: 367: 363: 359: 357: 353: 349: 347: 343: 339: 335: 331: 329: 325: 321: 319: 315: 311: 309: 305: 301: 299: 295: 278: 273: 269: 265: 263: 259: 255: 253: 249: 245: 243: 239: 235: 233: 229: 225: 223: 222:Crystal habit 219: 215: 211: 205: 203: 199: 194: 190: 186:(monoclinic) 185: 182: 180: 176: 171: 164: 162: 161:Crystal class 158: 152: 149: 147: 143: 139: 137: 133: 125: 123: 119: 115: 113: 109: 63: 57: 53: 50: 46: 45:Tectosilicate 43: 39: 34: 30: 25: 20: 1408: 1370:Spencer 1911 1365: 1320: 1316: 1310: 1298:. Retrieved 1293: 1289: 1279: 1216: 1183:. Retrieved 1176:the original 1049: 1045: 1035: 943: 912: 901: 885:Iceland-spar 869:Deccan Traps 849:Bay of Fundy 845:Isle of Skye 834: 780:cavities of 778:amygdaloidal 771: 758:hydrocarbons 751: 739: 702: 682: 679: 659: 614: 595: 579: 570:orthorhombic 566:mirror plane 555: 544: 476: 460:At one time 459: 414: 385: 384: 378: 332:2.12 to 2.22 202:Formula mass 188: 183: 1380:Attribution 1300:30 December 1257:stilbite-Na 1147:stilbite-Ca 865:apophyllite 853:Nova Scotia 768:Environment 546:Epistilbite 411:Stilbite-Na 408:Stilbite-Ca 340:Biaxial (−) 318:Diaphaneity 179:Space group 1434:Categories 1185:2010-07-29 1027:References 931:heulandite 921:Province, 908:laumontite 857:New Jersey 831:Localities 805:sandstones 558:monoclinic 496:stellerite 462:heulandite 375:References 366:Solubility 356:Fusibility 272:Mohs scale 170:H-M symbol 151:Monoclinic 112:IMA symbol 1296:: 387–397 1076:235729616 789:andesites 774:secondary 685:unit cell 586:triclinic 582:endmember 574:unit cell 520:barrerite 487:aluminium 1460:Zeolites 1401:Stilbite 1345:99122598 1194:cite web 946:Tertiary 939:rhyolite 935:andesite 923:Sardinia 919:Cagliari 897:Scotland 817:prehnite 782:basaltic 742:zeolites 655:fracture 651:Cleavage 629:hardness 621:cleavage 605:Twinning 601:cleavage 597:Crystals 494:between 386:Stilbite 275:hardness 262:Tenacity 252:Fracture 242:Cleavage 232:Twinning 140:77.1.4.3 41:Category 22:Stilbite 1407:(ed.). 1397::  1325:Bibcode 1054:Bibcode 891:in the 867:in the 837:Iceland 821:calcite 640:⁄ 483:silicon 479:cations 467:Germany 456:History 398:mineral 394:zeolite 287:⁄ 266:Brittle 56:Formula 49:Zeolite 36:General 1403:". In 1391:  1343:  1223:  1074:  873:Mumbai 825:quartz 793:gneiss 625:streak 617:luster 492:series 308:Streak 298:Luster 168:(same 1341:S2CID 1179:(PDF) 1172:(PDF) 1072:S2CID 954:Nasik 927:Italy 881:India 871:near 787:, in 592:Habit 538:·26(H 514:·28(H 312:White 213:Color 102:·28(H 80:·28(H 1302:2020 1221:ISBN 1200:link 944:The 915:Pula 877:Pune 859:and 823:and 813:tuff 807:and 795:and 748:Uses 726:.14H 683:The 580:Non- 542:O). 522:, Na 485:and 445:·28( 292:to 4 189:Amma 184:C2/m 1333:doi 1062:doi 937:or 631:is 526:(Si 502:(Si 116:Stb 90:(Si 68:(Si 1436:: 1353:^ 1339:. 1331:. 1321:82 1319:. 1294:55 1292:. 1288:. 1262:^ 1247:^ 1231:^ 1208:^ 1196:}} 1192:{{ 1152:^ 1133:^ 1112:^ 1084:^ 1070:. 1060:. 1050:85 1048:. 1044:. 941:. 925:, 917:, 899:. 879:, 851:, 847:, 843:, 839:, 827:. 819:, 791:, 764:. 730:O) 724:36 720:13 718:Si 714:Al 664:: 536:72 534:)O 530:Al 528:28 512:72 510:)O 506:Al 504:28 481:: 443:72 433:Al 430:27 427:Si 420:Ca 417:Na 153:, 106:O) 100:72 98:)O 94:Al 92:27 84:O) 78:72 76:)O 72:Al 70:27 47:, 1372:. 1347:. 1335:: 1327:: 1304:. 1273:. 1202:) 1188:. 1127:. 1078:. 1064:: 1056:: 728:2 722:O 716:5 712:2 642:2 638:1 635:+ 633:3 540:2 532:8 524:8 516:2 508:8 500:4 450:2 447:H 440:O 438:) 436:9 425:( 423:4 289:2 285:1 282:+ 280:3 172:) 104:2 96:9 88:9 82:2 74:9 66:4

Index


Tectosilicate
Zeolite
Formula
IMA symbol
Strunz classification
Dana classification
Crystal system
Monoclinic
Crystal class
H-M symbol
Space group
Formula mass
Crystal habit
Twinning
Cleavage
Fracture
Tenacity
Mohs scale
Luster
Streak
Diaphaneity
Specific gravity
Refractive index
Fusibility
Solubility
tectosilicate
zeolite
mineral
International Mineralogical Association

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