Knowledge

Deliming

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The acid present in the deliming agents neutralizes the process liquor pH. Typical values after effective, thorough deliming will range from 6 to 9. Ammonium salt deliming pH values should be pH 8 to 9.
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The deliming process can be done with acids that can be rapid in their pH adjustment. Buffering salts like ammonium salts predominated the 20th century.
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Deliming operations of cattle hides usually last two hours and are generally associated with the alkaline phase of
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The ammonium ion is then free to penetrate the pelt cross-section and further ionise to act as an acid:
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processing is a drum/paddle or pit based operation where two main objectives are met:
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As an acid is added it lowers the pH value of the internal pelt solution. This
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can be used as deliming agents and they follow the following chemistry:
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Lowering of the liquor pH to the values used in the bating process.
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the solution alkalinity. The lowering of the pH results in rapid
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of process liquors and in the cutting of a pelt cross-section.
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is used to monitor deliming pelt cross-sectional progress.
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The protons can then serve two functions, namely to
35:from the pelt and the consequent deswelling of the 692: 261:, Leather Producer's Association, p. 104, 293: 240:can also be used but their use is limited. 300: 286: 256: 79: 693: 281: 204:Other weak acids can be used such as 62:Removal of pelt alkali and deswelling 13: 14: 712: 197:basic groups of the collagen and 89: 588:Artificial leather / Leatherette 654:British Museum leather dressing 250: 1: 259:Leather Technician's Handbook 243: 75:of the collagen basic groups. 16:Process in leather processing 7: 649:Leather Archives and Museum 307: 201:solution alkali chemicals. 10: 717: 670:History of hide materials 662: 626: 580: 552: 514: 416: 315: 257:Sharphouse, J.H. (1983), 639:Igualada Leather Museum 232:. Strong acids such as 230:carbon dioxide deliming 644:Walsall Leather Museum 634:German Leather Museum 80:Lowering of liquor pH 48:beamhouse operations 675:Leather subculture 688: 687: 234:hydrochloric acid 100:ammonium chloride 708: 302: 295: 288: 279: 278: 272: 271: 254: 164: 163: 162: 141: 140: 139: 125: 124: 123: 96:Ammonium sulfate 716: 715: 711: 710: 709: 707: 706: 705: 691: 690: 689: 684: 658: 627:Leather museums 622: 576: 572:Leather carving 567:Cuir de Cordoue 548: 510: 417:Leather sources 412: 311: 306: 276: 275: 269: 255: 251: 246: 222:phosphoric acid 184: 176: 172: 161: 158: 157: 156: 154: 138: 135: 134: 133: 131: 122: 119: 118: 117: 115: 113: 109: 92: 82: 64: 56:Phenolphthalein 17: 12: 11: 5: 714: 704: 703: 686: 685: 683: 682: 677: 672: 666: 664: 660: 659: 657: 656: 651: 646: 641: 636: 630: 628: 624: 623: 621: 620: 615: 610: 605: 600: 595: 590: 584: 582: 578: 577: 575: 574: 569: 564: 558: 556: 550: 549: 547: 546: 541: 536: 531: 526: 520: 518: 512: 511: 509: 508: 503: 498: 493: 488: 483: 478: 473: 468: 463: 458: 453: 448: 447: 446: 441: 431: 426: 420: 418: 414: 413: 411: 410: 405: 403:Shell cordovan 400: 395: 390: 385: 380: 375: 370: 365: 360: 355: 350: 345: 340: 335: 330: 325: 319: 317: 313: 312: 305: 304: 297: 290: 282: 274: 273: 267: 248: 247: 245: 242: 191: 190: 182: 174: 170: 159: 148: 147: 136: 120: 111: 107: 91: 90:Deliming types 88: 87: 86: 81: 78: 77: 76: 63: 60: 44: 43: 40: 15: 9: 6: 4: 3: 2: 713: 702: 701:Leathermaking 699: 698: 696: 681: 678: 676: 673: 671: 668: 667: 665: 661: 655: 652: 650: 647: 645: 642: 640: 637: 635: 632: 631: 629: 625: 619: 616: 614: 611: 609: 606: 604: 601: 599: 596: 594: 591: 589: 586: 585: 583: 579: 573: 570: 568: 565: 563: 560: 559: 557: 555: 551: 545: 542: 540: 537: 535: 532: 530: 527: 525: 522: 521: 519: 517: 513: 507: 504: 502: 499: 497: 494: 492: 489: 487: 484: 482: 479: 477: 474: 472: 469: 467: 464: 462: 459: 457: 454: 452: 449: 445: 442: 440: 437: 436: 435: 432: 430: 427: 425: 422: 421: 419: 415: 409: 406: 404: 401: 399: 396: 394: 391: 389: 386: 384: 381: 379: 376: 374: 371: 369: 366: 364: 361: 359: 356: 354: 351: 349: 346: 344: 341: 339: 336: 334: 331: 329: 326: 324: 321: 320: 318: 314: 310: 303: 298: 296: 291: 289: 284: 283: 280: 270: 268:0-9502285-1-6 264: 260: 253: 249: 241: 239: 238:sulfuric acid 235: 231: 227: 226:carbonic acid 223: 219: 215: 211: 207: 202: 200: 196: 188: 180: 168: 153: 152: 151: 145: 129: 105: 104: 103: 101: 97: 84: 83: 74: 70: 66: 65: 59: 57: 53: 49: 41: 38: 34: 30: 29: 28: 26: 23:operation in 22: 528: 258: 252: 203: 192: 149: 93: 45: 20: 18: 581:Substitutes 562:Bookbinding 363:Law leather 218:lactic acid 214:formic acid 210:acetic acid 73:protonation 69:neutralizes 31:Removal of 608:Ultrasuede 353:Corinthian 244:References 206:boric acid 199:neutralize 613:Alcantara 603:Presstoff 598:Naugahyde 516:Processes 451:Crocodile 424:Alligator 398:Shearling 195:protonate 187:hydronium 52:pH values 695:Category 554:Crafting 529:Deliming 476:Kangaroo 439:Calfskin 393:Shagreen 343:Buckskin 167:ammonium 128:ammonium 21:deliming 680:Rawhide 663:Related 618:Clarino 539:Tanning 481:Ostrich 368:Morocco 358:Kidskin 348:Chamois 323:Aniline 309:Leather 179:ammonia 144:sulfate 25:leather 544:Oiling 534:Bating 524:Liming 434:Cattle 388:Russia 383:Patent 378:Nubuck 338:Bonded 333:Boiled 328:Bicast 265:  173:O → NH 37:fibres 33:alkali 593:Kirza 501:Snake 496:Sheep 471:Horse 444:Slunk 429:Bison 408:Suede 316:Types 181:) + H 169:) + H 491:Seal 466:Goat 456:Deer 373:Napa 263:ISBN 236:and 224:and 130:) + 98:and 19:The 506:Yak 486:Pig 461:Eel 185:O ( 110:)SO 106:(NH 697:: 220:, 216:, 212:, 208:, 155:NH 132:SO 116:NH 114:→ 301:e 294:t 287:v 189:) 183:3 177:( 175:3 171:2 165:( 160:4 146:) 142:( 137:4 126:( 121:4 112:4 108:4 39:.

Index

leather
alkali
fibres
beamhouse operations
pH values
Phenolphthalein
neutralizes
protonation
Ammonium sulfate
ammonium chloride
ammonium
sulfate
ammonium
ammonia
hydronium
protonate
neutralize
boric acid
acetic acid
formic acid
lactic acid
phosphoric acid
carbonic acid
carbon dioxide deliming
hydrochloric acid
sulfuric acid
ISBN
0-9502285-1-6
v
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